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Question

In the reaction series: C6H5ClNH3−−−−−−−Cu2O,200oCX;XHNO2−−−050CZ;X+ZA, the number of σ and π bonds in A are:
  1. 25σ and 6π
  2. 25σ and 7π
  3. 27σ and 7π
  4. 27σ and 6π

A
25σ and 7π
B
25σ and 6π
C
27σ and 7π
D
27σ and 6π
Solution
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Nucleophilic substitution of chloro-benzene with ammonia gives aniline.

C6H5ClNH3−−−−−−−Cu2O,2000CC6H5NH2X+HCl

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