Before grounding, let charges on A and B be qA and qB respectively, and radius be rA and rB respectively.
So, VA=kqA/rA+kqB/rB
and, VB=kqA/rB+kqB/rB
where k=1/4πϵo
After grounding of B, let charges on A and B be q′A and q′B respectively.
As A is isolated, q′A=qA
Now, new potential on spheres are:
V′A=kq′A/rA+kq′B/rB=kqA/rA+kq′B/rB
and, V′B=kq′A/rB+kq′B/rB=kqA/rB+kq′B/rB=0⇒q′B=−qA
So, V′A=kqA/rA−kqA/rB=kqA/rA+kqB/rB−(kqA/rB+kqB/rB)=VA−VB