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Question

Match column-I with column-II and select the correct answer using the codes given below the lists.

Solution
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Allotropes of sulfur:
(A) Engel's sulfur is the sulfur ring in cycloS6. It has a "chair" conformation, reminiscent of the chair form of cyclohexane. All of the sulfur atoms are equivalent. Hence, A matches to 1.
(B) Rhombic sulfur is yellow solid consisting of S8 puckered rings. The thermodynamically stable form at ordinary temperatures. Hence, B matches to 4.
(C) Monoclinic sulphur is yellow crystalline solid, consisting of S8 puckered rings. Hence, C matches to 3.
(D) The most commonly encountered form of sulfur is the orthorhombic polymorph of $ S_8$, which adopts a puckered ring or "crown" structure. Hence, D matches to 2.

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