Match the column I with column II and mark the appropriate choice.
Column I
Column II
(A)
CH3NH2+CHCl3+KOHΔ−→
(i)
CH3NH2
(B)
CH3CONH2+Br2+KOH→
(ii)
CH3OH
(C)
CH3NH2+NaNO2+HCl→
(iii)
CH3NHCH3
(D)
CH3NC+4HPt−→
(iv)
CH3NC
(A)→(i),(B)→(ii),(C)→(iii),(D)→(iv)
(A)→(iv),(B)→(i),(C)→(ii),(D)→(iii)
(A)→(iii),(B)→(iv),(C)→(i),(D)→(ii)
(A)→(ii),(B)→(iii),(C)→(iv),(D)→(i)
A
(A)→(iv),(B)→(i),(C)→(ii),(D)→(iii)
B
(A)→(i),(B)→(ii),(C)→(iii),(D)→(iv)
C
(A)→(ii),(B)→(iii),(C)→(iv),(D)→(i)
D
(A)→(iii),(B)→(iv),(C)→(i),(D)→(ii)
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Solution
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Carbylamine reaction:
(A) CH3NH2+CHCl3+KOHΔ−→CH3NC
Hoffman Bromamide reaction:
(B) CH3CONH2+Br2+KOH→CH3NH2
Reaction with HNO2
(c) CH3NH2+NaNO2+HCl→CH3OH
Reduction with H2/Pt:
(D) CH3NC+4HPt/Pd−−−−→CH3NHCH3
Option C is correct.
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