Kp=P2NO2PN2O4=0.420.6=0.266.
Now total pressure is 0.1 atm.
N2O4⇌NO2
Equilibrium moles are 1−x and 2x
Mole fraction are 1−x1+x, 2x1+x
The expression for the equilibrium constant is Kp=P2NO2PN2O4. 0.266=(2x1+x)2(1−x1+x)×0.1. Thus x=0.87. Hence, the degree of dissociation is 87%.