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Question

Na2S+Na2[Fe(CN)5NO]X(purplecolor)

What is the formula of X?

  1. [Fe(H2O)5NO]SO4
  2. Na4[Fe(CN)5(NOS)]
  3. Fe4[Fe(CN)6]
  4. [Fe(H2O)2NO]SO4

A
[Fe(H2O)5NO]SO4
B
Na4[Fe(CN)5(NOS)]
C
Fe4[Fe(CN)6]
D
[Fe(H2O)2NO]SO4
Solution
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With sodium nitroprusside solution, ionic sulphide gives a purple colour in alkaline medium.

Na2S+Na2[Fe(CN)5NO]Na4[Fe(CN)5NOS]Purple colour

Here X is Na4[Fe(CN)5(NOS)].

Option (D) is correct.

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