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Question

Order of stability of the ions of Ge, Sn and Pb is :
  1. Ge2+<Sn2+<Pb2+
  2. Ge4+<Sn4+<Pb4+
  3. Pb2+<Pb4+
  4. Sn4+<Sn2+

A
Ge4+<Sn4+<Pb4+
B
Ge2+<Sn2+<Pb2+
C
Sn4+<Sn2+
D
Pb2+<Pb4+
Solution
Verified by Toppr

On moving down the group IV A, the stability of +2 oxidation state increases due to inert pair effect which becomes more pronounced in heavier elements.

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Similar Questions
Q1

Stability of ions of Ge,Sn, and Pb will be in the order:


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Q2
The correct code for stability of oxidation states of Sn and Pb is :
[1]Pb2+>Pb4,Sn2+>Sn4+

[2]Pb2+<Pb4,Sn2+<Sn4+

[3]Pb2+>Pb4,Sn2+<Sn4+

[4]Pb2+<Pb4,Sn2+>Sn4+

[5]Sn2+<Pb2+,Sn4+>Pb4+

[6]Sn2+<Pb2+,Sn4+<Pb4+

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Q3
Which of the following reactions are spontaneous?
(a) Pb4++Sn2+Sn4++Pb2+

(b) Sn4++Pb2+Pb4++Sn2+

(EoPb4+/Pb2+=1.69 V,EoSn4+/Sn2+=0.15 V)

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Q4
Which of the following reaction are possible?
(i) Sn2++2Hg2+Hg2+2+Sn4+
(ii) Ge2++Pb4+pb2++Ge4+
(iii) T1++Ga3+Ga++T13+
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Q5

It is because of the inability of ns2 electrons of the valence shell to participate in bonding that


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