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Question

Reason
$$PCl_5$$ in solid state consists of tetrahedral $$PCl_{4}^{+}$$ cation and octahedral $$PCl_{6}^{-}$$ anion
Assertion
$$PCl_5$$ is covalent in gaseous and liquid states but ionic in solid state.

A
Both Assertion and Reason are incorrect
B
Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
C
Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
D
Assertion is correct but Reason is incorrect
Solution
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Correct option is B. Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
Both Assertion and reason are true and reason is not the correct explanation of assertion.

$$PCl_5$$ is trigonal bipyramidal containing $$sp^3d$$ hybridized $$P$$ atom in liquid and gaseous state. Wherease in solid state it consists of tertahedral $$PCl_4^+$$ cation octahedral $${ PCl }_{ 6 }^{ - }$$ anion.

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Similar Questions
Q1
Reason
$$PCl_5$$ in solid state consists of tetrahedral $$PCl_{4}^{+}$$ cation and octahedral $$PCl_{6}^{-}$$ anion
Assertion
$$PCl_5$$ is covalent in gaseous and liquid states but ionic in solid state.
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Q2
Assertion :PCl5 is a covalent in gaseous and liquid states but ionic in solid state. Reason: PCl5 in solid state consists of tetrahedral PCl+4 cation and octahedral PCl6 anion.
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Q3

In solid state PCl5 exists as


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Q4
In solid state PCl5 exist as an ionic solid [PCl4]+[PCl6] hybridisation state of cation and anion respectively :
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Q5
Phosphorous pentachloride in gaseous phase exists as a monomer. In solid state, it exists as PCl+4 ions. The hybrid state of P-atom in PCl5 is sp3d The hybrid states of P - atoms in PCl+4 and PCl6 will be:

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