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Question

PCl5(g)PCl3(g)+Cl2(g),

For the above given reaction the forward reaction at constant temperature is favoured by:

  1. introducing an inert gas at constant volume
  2. introducing chlorine gas at constant volume
  3. introducing an inert gas at constant pressure
  4. introducing PCl5 at constant volume

A
introducing an inert gas at constant volume
B
introducing PCl5 at constant volume
C
introducing an inert gas at constant pressure
D
introducing chlorine gas at constant volume
Solution
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A. When an inert gas is added to the system in equilibrium at constant volume, the total pressure will increase. But the concentrations of the products and reactants will not change.

Hence, when an inert gas is added to the system in equilibrium at constant volume there will be no effect on the equilibrium.

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