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Question

Permanent hardness of water can be removed by:

A
heating
B
treating with sodium acetate $$(CH_2CO_2Na)$$
C
treating with $$Ca(HCO_3)_2$$
D
treatment with sodium hexametaphosphate $$(Na_6P_6O_{18}$$)
Solution
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Correct option is D. treatment with sodium hexametaphosphate $$(Na_6P_6O_{18}$$)
The permanent hardness of water can be removed by using Calgon process.

$$Na_2[Na_4(PO_3)_6]+2Ca^{2+}/Mg^{2+}\rightarrow \underset{\text{soluble complex}}{Na_2[Ca_2/Mg_2(PO_3)_6]}+4Na^+$$

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