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Question

Select the correct statement about elements of group 15:
  1. The order of stability of oxidation state for +3 is Bi3+>Sb3+ and for +5 is Bi5+<Sb5+<As5+
  2. In the case of nitrogen, all oxidation states from +1 to +4 tend to disproportionate in acid solution
  3. All of these.
  4. There is a considerable increase in covalent radius from N to P but from As to Bi only a small increase in covalent radius is observed.

A
The order of stability of oxidation state for +3 is Bi3+>Sb3+ and for +5 is Bi5+<Sb5+<As5+
B
In the case of nitrogen, all oxidation states from +1 to +4 tend to disproportionate in acid solution
C
All of these.
D
There is a considerable increase in covalent radius from N to P but from As to Bi only a small increase in covalent radius is observed.
Solution
Verified by Toppr

As we move down the group, lower oxidation state become stable due to inert pair effect.

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