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Question

Sodium thiosulphate, Na2S2O35H2O is used in photography to :
  1. reduce the silver bromide to metallic silver
  2. remove undecomposed AgBr as soluble thiosulphate complex
  3. convert the metallic silver to silver salt
  4. remove reduced silver

A
reduce the silver bromide to metallic silver
B
remove undecomposed AgBr as soluble thiosulphate complex
C
convert the metallic silver to silver salt
D
remove reduced silver
Solution
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Silver bromide reacts with sodium thiosulphate solution to form sodium argentothiosulphate Na3[Ag(S2O3)2] which is water-soluble.

AgBr(s)+2Na2S2O3Na3[Ag(S2O3)2]

Thus, undecomposed AgBr can be removed as soluble thiosulphate complex.

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