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Solid ammonium carbamate dissociated into NH3 and CO2 as : NH4COONH2(s)2NH3(g)+CO2(g). The total pressure at equilibrium is 0.225 atm. Kp is X×103atm3. 1000X is__________.

Solution
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Total pressure =2P+P=3P=0.225atm
P=0.075atm
2P=0.15atm
KP=P2NH3PCO2=(0.150.15atm)2×0.0750.15atm
KP=1.687×103atm3=X×103atm3
X=1.687
1000X=1687

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