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Question

Sulphuryl chloride (SO2Cl2) reacts with white phosphorus (P4) to give:
  1. OPCl3,SOCl2
  2. PCl5,SO2,S2Cl2
  3. OPCl3,SO2,S2Cl2
  4. PCl5,SO2

A
OPCl3,SOCl2
B
PCl5,SO2
C
PCl5,SO2,S2Cl2
D
OPCl3,SO2,S2Cl2
Solution
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Sulphuryl chloride (SO2Cl2) reacts with white phosphorus (P4) to give phosphorous pentachloride and sulphur dioxide.

10SO2Cl2+P44PCl5+10SO2

Hence, option A is correct.

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