Correct option is A. 135
Mass defect $$\Delta m = 226.005 - 222.000 - 4.000$$
$$= 0.005 \, amu$$
$$\therefore Q $$ value = $$0.005 \times 931.5 = 4.655 MeV$$
Also $$\dfrac{K.E_{\alpha}}{K.E_{Rn}} = \dfrac{m_{Rn}}{m_{\alpha}}$$
$$\Rightarrow K.E_{Rn} = \dfrac{m_{\alpha}}{m_{Rn}} . K.E_{\alpha} = \dfrac{4}{222} \times 4.44 = 0.08 MeV$$
$$\therefore$$ Energy of $$\gamma$$-Photon = $$4.655 - (4.44 + 0.08)$$
$$= 0.135 MeV = 135 KeV$$