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Question

The best solvent for the crystallization of organic solid is in which:
  1. compound is insoluble
  2. organic compound is highly soluble
  3. compound is soluble on warming
  4. compound is soluble at 900

A
compound is insoluble
B
compound is soluble at 900
C
organic compound is highly soluble
D
compound is soluble on warming
Solution
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Generally speaking you need to take polar solvents for polar compound and nonpolar solvents for nonpolar compounds. Many times a mixture of solvents works better. Once you have this basic idea, crystallization is a skill developed over a period of time by trial and error process. Even after long experience you may not hit the right solvent in the first try.

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