Albert Magnus was first to notice the difference between monocots and dicots and between stem structure.
Andrea Caesalpino was a herbalist and gave more importance to organs of fructification in plant classification rather than the plant habits.
Pedanius Dioscorides was a botanist, he wrote the book De Materia Medica which is a 5-volume encyclopaedia about herbal medicine and related medicinal substances.
Thus, the correct answer is option B.