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Question

The bond angle in PH3 is:
  1. much lesser than NH3
  2. equal to that in NH3
  3. much greater than in NH3
  4. slightly more than in NH3

A
much greater than in NH3
B
slightly more than in NH3
C
equal to that in NH3
D
much lesser than NH3
Solution
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As electronegativity of P is much lower than N, so in NH3 nitrogen attracts all bond electron towards the centre and electron-electron repulsion is higher so it has a higher bond angle. Bond angle in ammonia is 107 & that in phosphene is 93.5.

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