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Question

The brown ring test for nitrates depends on:
  1. oxidizing action of sulphuric acid.
  2. the reduction of nitrate to nitric oxide.
  3. reduction of ferrous sulphate to iron.
  4. oxidation ofnitric oxide to nitrogen dioxide.

A
oxidation ofnitric oxide to nitrogen dioxide.
B
oxidizing action of sulphuric acid.
C
the reduction of nitrate to nitric oxide.
D
reduction of ferrous sulphate to iron.
Solution
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The brown ring test for nitrates depends on the reduction of nitrate to nitric oxide.

NO3+3Fe2++4H+3Fe3++NO+2H2O

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(a) Explain with the help of a balanced equation, the brown ring test for nitric acid.

(b) Why is freshly pepared ferrous sulphate solution used for testing the nitrate radical in the brown ring test ?

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