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Question

The correct statements among (a) to (d) are:
(a) saline hydrides produce $$H_{2}$$ gas when reacted with $$H_{2}O$$.
(b) Reaction of $$LiAlH_{4}$$ with $$BF_{3}$$ leads to $$B_{2}H_{6}$$.
(c) $$PH_{3}$$ and $$CH_{4}$$ are electron - rich and electron - precise hydrides, respectively.
(d) $$HF$$ and $$CH_{4}$$ are called as molecular hydrides.

A
(a), (b), (c) and (d)
B
(a), (c) and (d) only
C
(c) and (d) only
D
(a), (b) and (c) only
Solution
Verified by Toppr

Correct option is C. (a), (b), (c) and (d)
(a) $$\underset {Ionic\ hydride/ saline\ hydride}{\overset {\oplus}{M} \overset {\ominus}{H} + HOH} \rightarrow MOH + H_{2}$$
(b) $$4BF_{3} + 3LiAlH_{4}\rightarrow 2B_{2}H_{6} + 3LiF + 3AlF_{3}$$
(C) Ref, image.

(d) $$HF$$ and $$CH_{4}$$ are molecular hydride because they are covalent molecules.

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Similar Questions
Q1
The correct statements among (a) to (d) are:
(a) saline hydrides produce $$H_{2}$$ gas when reacted with $$H_{2}O$$.
(b) Reaction of $$LiAlH_{4}$$ with $$BF_{3}$$ leads to $$B_{2}H_{6}$$.
(c) $$PH_{3}$$ and $$CH_{4}$$ are electron - rich and electron - precise hydrides, respectively.
(d) $$HF$$ and $$CH_{4}$$ are called as molecular hydrides.
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Q2
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The various types of hydrides and examples of each type are given below :
Hydride type Compound
A Electron deficient i LiH
B Saline ii CH4
C Electron-precise iii NH3
D Interstitial iv B2H6
E Electron rich v CrH
Choose the correct matching from the code given below :
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Q3
Molecular hydrides are classified as electron deficient, electron precise and electron-rich compounds. Explain each type with two examples
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Q4
Arrange the following hydrides in their increasing acid strength [CH4, H2S, PH3 and SiH4] -
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Q5
Match the column I with column II and mark the appropriate choice.
column Icolumn II
ANaHiInterstitial hydride
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CVH0.56iiiIonic hydride
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