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Question

The dissociation equilibrium of a gas AB2 can be represented as:

2AB2(g)2AB(g)+B2(g)

The degree of dissociation is x and is small compared to 1. The expression relating the degree of dissociation x with equilibrium constant Kp and total pressure p is:

  1. (2Kp/p)1/3
  2. (Kp/p)
  3. (2Kp/p)1/2
  4. (2Kp/p)

A
(2Kp/p)1/3
B
(2Kp/p)1/2
C
(Kp/p)
D
(2Kp/p)
Solution
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Let P be the initial pressure of AB2
The equilibrium pressures of AB2, AB and B2 are P(1x), xP and 0.5xP respectively.

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