In moving from left to right in a period the atomic volume first decreases and then incrases because-
- As we move left to right in a period , one electron and one proton gets added .
- Initially , the increase in nuclear charge overcomes the increase in the no. of electrons. Hence the atomic volume decreases.
- But in the right of the priodic table newly added electrons goes into the p orbital and due to high shielding power of s and p orbitals , atomic volume increase.
Atomic volume of Boron is least