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Question

The energy barrier to free rotation about carbon carbon bond of ethane is about:
  1. 40 kJ mol1
  2. 30 kJ mol1
  3. 3 kcal mol1
  4. 3 kJ mol1

A
3 kcal mol1
B
40 kJ mol1
C
30 kJ mol1
D
3 kJ mol1
Solution
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The staggered structure is the structure of lower energy than eclipsed structure. The relative energy required for complete a rotation in ethane is called the energy barrier to rotation, and it is about 3 kcal/mol. That is, the eclipsed structure is 3 kcal higher in energy than the staggered structure.

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