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Question

The maximum current can be drawn from which of the following cells?
  1. Zn(s)|Zn2+(0.2M)|| Cu2+(0.2M)|Cu(s)
  2. Zn(s)|Zn2+(0.002M)||Cu2+ (0.2M)|Cu(s)
  3. Zn(s)|Zn2+(0.2M)||Cu2+(0.002M)|Cu(s)
  4. All of these

A
Zn(s)|Zn2+(0.2M)|| Cu2+(0.2M)|Cu(s)
B
All of these
C
Zn(s)|Zn2+(0.2M)||Cu2+(0.002M)|Cu(s)
D
Zn(s)|Zn2+(0.002M)||Cu2+ (0.2M)|Cu(s)
Solution
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Q1

For cell reaction, Zn+Cu2+Zn2++Cu, cell representation is


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Q2
What is the voltage of the voltaic cell Zn|Zn2+||Cu2+|Cu at 298 K if [Zn2+]=0.2 M and [Cu2+]=4.0 M?
Cu2++2eCu E=+0.34V
Zn2++2eZn E=0.76 V
[Note: E=E(0.0591/n)(logQ)
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Q3

The cell representation of the given reaction is:
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Q4
Calculate EoCell value of the following reactions:

Zn(s)+Cu2+(aq)Zn2+(aq)+Cu(s)

[Given: ECu2+/Cu=0.34V,EZn2+/Zn=0.76V]

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Q5
E1,E2,E3 are the emf values of the three galvanic cells respectively.
(i) Zn|Zn2+1M||Cu2+0.1M|Cu
(ii) Zn|Zn2+1M||Cu2+1M|Cu
(iii) Zn|Zn2+0.1M||Cu2+1M|Cu
Which one of the following is true?
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