The order of reactivity of alcohols towards hydrogen halide is :
benzyl>30>20>10
30>benzyl>20>10
30>20>10>benzyl
30>20>benzyl>10
A
30>20>benzyl>10
B
30>benzyl>20>10
C
30>20>10>benzyl
D
benzyl>30>20>10
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Solution
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Greater the stability of carbocation formed, greater is the reactivity. Benzyl carbocation is resonance stabilized.
∴tertiary>benzyl>secondary>primary
Option B is correct.
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