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Question

The order of reactivity of Phenyl Magnesium Bromide with the following compounds is:
43360_8713b0da206b4eb1b84abe84500f16fa.png
  1. (II)>(III)>(I)
  2. (I)>(III)>(II)
  3. (II)>(I)>(III)
  4. All react with the same rate

A
(II)>(III)>(I)
B
(I)>(III)>(II)
C
All react with the same rate
D
(II)>(I)>(III)
Solution
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Nucleophile attacks the most electrophilic site first. Among aldehyde and a ketone, aldehydes are more electrophilic as in ketones the + charge on carbonyl carbon is decreased by +I effect of both alkyl groups.

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