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Allotropes of Phosphorus

Question

The product formed in the reaction of ${S O C l}_{2}$ with white phosphorus is ?
${S C l}_{2}$
${P O C l}_{3}$
${S o}_{2} {C l}_{2}$
${P C l}_{3}$

A

{S C l}_{2}

B

{P C l}_{3}

C

{S o}_{2} {C l}_{2}

D

{P O C l}_{3}

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Solution

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The reaction involved is
$P_{4} + 8 S O C l_{2} ⟶ 4 P C l_{3} + 4 S O_{2} + 2 S_{2} C l_{2}$
Phosphorous trichloride is the product formed when $S O C l_{2}$ reacts with white phosphorous.

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Paragraph 2
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