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Question

The products obtained when chlorine gas reacts with cold and dilute aqueous NaOH are:
  1. Cl and ClO2
  2. ClO and ClO3
  3. Cl and ClO
  4. ClO2 and ClO3

A
ClO2 and ClO3
B
Cl and ClO
C
Cl and ClO2
D
ClO and ClO3
Solution
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Case -1: Hot Concentrated NaOH

The reaction between chlorine and hot concentrated sodium hydroxide solution is:

NaOH+Cl25NaCl+NaClO3+3H2O

Case -2:Cold NaOH

The reaction between chlorine and cold dilute sodium hydroxide solution is:

2NaOH+Cl2NaCl+NaClO+H2O

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Similar Questions
Q1
The products obtained when chlorine gas reacts with cold and dilute aqueous NaOH are:
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Q2
Reaction 3ClOClO2+2Cl
(i) ClO+ClOK1ClO2+Cl (Slow step)
(ii) ClO2+ClOK2ClO3+Cl (Fast step)
then the rate of given reaction = ______
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Q3
Reaction, 3ClOClO3+2Cl occurs in following two steps.
I. ClO+ClOK1ClO2+Cl(Slow step)
II. ClO+2ClOk2ClO3+Cl (Fast step)
Then, the rate of given reaction is:
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Q4
For the reaction:
3ClOClO3+2Cl
Mechanism:
ClO+ClOClO2+Cl(slow)
ClO2+ClOClO3+Cl(fast)

The rate of reaction of given reaction is given by ___________.

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Q5
The correct order of ClO bond lengths in ClO,ClO2,ClO3and ClO4 is:
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