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Question

The solution in a beaker turns blue if:
  1. Cu electrode is placed in ZnSO4 solution
  2. Cu electrode is placed in AgNO3 solution
  3. Cu electrode is placed in Al2(SO4)3 solution
  4. Cu electrode is placed in FeSO4 solution

A
Cu electrode is placed in AgNO3 solution
B
Cu electrode is placed in FeSO4 solution
C
Cu electrode is placed in ZnSO4 solution
D
Cu electrode is placed in Al2(SO4)3 solution
Solution
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Order of reduction potential of given metals is:

Al<Zn<Fe<Cu<Ag

Only Ag will get reduced easily than Cu. Therefore, copper metal in the presence of Ag will get oxidise as:

Cu+2Ag+Cu2++2Ag
where,
AgNO3Ag++NO3

Thus obtained the solution of copper ions is blue in colour.

Therefore the solution in a beaker turns blue if Cu electrode is placed in AgNO3 solution.

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