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Question

The temperature coefficient of the e.m.f. of cell, (dEdT)p is given by:

(A) nFS

(B) SnF

(C) SnFT

(D) nFE

A
SnFT
B
nFE
C
nFS
D
SnF
Solution
Verified by Toppr

As we know,

Ecell=ΔGnF


ΔG=ΔSdT

The temperature coefficient (dEdT)=ΔS/dTdT.nF=ΔSnF

Hence, option (B) is correct.

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Similar Questions
Q1
d(ΔG)=(ΔSreaction).dT
ΔG=ΔHTΔS
ΔG=ΔH+T(d(ΔG)dT)P
The temperature coefficient of the e.m.f of a cell, (dEdT)P is given by:
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Q2

The temperature coefficient of the e.m.f. of cell, (dEdT)p is given by:

(A) nFS

(B) SnF

(C) SnFT

(D) nFE

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Q3
The cell potential (Ecell) of a reaction is related as ΔG=nF Ecell, where ΔG represents maximum useful electrical work.
n = no. of moles of electrons exchanged during the reaction.
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Q5
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