In photoelectric effect, energy is conserved.
In photoelectric effect, Einstein's equation is given by
Photon energy = kinetic energy of electron + work function
i.e. hv=eVs+hv0
where, Vs is the stopping potential and v0 is the threshold frequency.
∴Vs=he(v−v0) .....(i)
Given, v0=3.3×1014Hz, v=8.2×1014Hz
h=6.6×10−34J−s, e=1.6×10−19C
Substituting these values in equation (i), we get
Vs=6.6×10−34(8.2×1014−3.3×1014)1.6×10−19
Vs=6.6×4.91.6×10−1=2V
⇒Vs=2V