The two hydrocarbons can be easily distinguished by simple chemical tests, as ethyne molecule is supposed to have acidic hydrogen.
1. When ethyne is bubbled through ammoniacal silver nitrate solution, a yellow-white precipitate of silver acetylide would be formed.
+ = +
2. Similarly, ethyne forms a red precipitate of copper acetylide () when it is passed through ammoniacal cuprous chloride solution.
Ethene does not react with or solution.
Hence, the correct option is