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Question

Very pure hydrogen (99.9%) can be made by which of the following processes?
  1. Reaction of methane with steam
  2. Mixing natural hydrocarbons of high molecular weight
  3. Reaction of salt like hydrides with water
  4. Electrolysis of water

A
Electrolysis of water
B
Reaction of salt like hydrides with water
C
Mixing natural hydrocarbons of high molecular weight
D
Reaction of methane with steam
Solution
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Pure hydrogen can be obtained from the electrolysis of water.

Cathode (reduction): 2H2O(l)+2eH2(g)+2OH(aq)

Anode (oxidation): 4OH(aq)O2(g)+2H2O(l)+4e

Combining either half reaction pair yields the same overall decomposition of water into oxygen and hydrogen:

Overall reaction: 2H2O(l)2H2(g)+O2(g)

The number of hydrogen molecules produced is thus twice the number of oxygen molecules.

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