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Question

What is the change in oxidation number of carbon in the following reaction?
$$CH_4 (g) + 4Cl_2 (g)\longrightarrow CCl_4 (l) + 4HCl(g)$$

A
$$0$$ to $$+ 4$$
B
$$-4$$ to $$+ 4$$
C
$$0$$ to $$-4$$
D
$$+4$$ to $$+ 4$$
Solution
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Correct option is B. $$-4$$ to $$+ 4$$
$$\overset {-4} CH_4 (g) + 4Cl_2 (g)\longrightarrow \overset {+4} CCl_4 (l) + 4HCl(g)$$
The oxidation state of $$H$$ and $$Cl$$ are +1 and -1 respectively. Therefore the oxidation state of C in methane is $$-4$$ and that in carbon tetrachloride is $$+4$$.

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