What is the difference between physisorption and chemisorption?
Physisorption (Physical adsorption)
| Chemisorption (Chemical adsorption)
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Weak van der Waals forces are present between the adsorbate molecules and the adsorbent.
| Strong chemical forces similar to chemical bonds are present between the adsorbate molecules and the adsorbent. |
The enthalpy of adsorption is low (20 to 40 kJ/mol).
| The enthalpy of adsorption is high (40 to 400 kJ/mol).
|
Occurs at low temperature and decreases with an increase in temperature.
| Occurs at high temperature and increases with increase in temperature.
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It is reversible.
| It is irreversible.
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No significant activation energy is required.
| Usually, high activation energy is required.
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It forms multimolecular layers.
| It forms unimolecular layers.
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