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Question

What may be expected to happen when phosphine gas is mixed with chlorine gas?
  1. PCl3 and HCl are formed and the mixture warms up.
  2. PCl3 and HCl are formed and the mixture cools down.
  3. The mixture only cools down.
  4. None of the above.

A
The mixture only cools down.
B
PCl3 and HCl are formed and the mixture warms up.
C
PCl3 and HCl are formed and the mixture cools down.
D
None of the above.
Solution
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PH3 is highly poisonous it explodes with traces of oxidizing agent like HNO3, Cl2 and Br2 vapors.

PH3+3Cl2PCl3+3HCl; ΔH=ve

Hence, PCl3 and HCl are formed and the mixture warms up as heat is evolved.

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