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Question

When concentrated HCl is added to an a queous solution of CoCl2, its colour changes from reddish pink to deep blue. Which complex ion gives colour in this reaction?
  1. [CoCl6]4
  2. [CoCl6]3
  3. [Co(H2O)6]2+
  4. [CoCl4]2

A
[CoCl6]4
B
[Co(H2O)6]2+
C
[CoCl4]2
D
[CoCl6]3
Solution
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When concentrated HCl is added to an aqueous solution of CoCl2, its colour changes from reddish pink to deep blue. Co(II) is oxidized to Co(III).
This indicates the formation of [CoCl6]3.
CoCl2HCl[CoCl6]3.

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