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Question

Which of the following are correct statements ?
  1. van der Waals constant a is a measure of attractive force
  2. van der Waals constant b is also called co-volume or excluded volume
  3. b is expressed in L mol1
  4. a is expressed in atm L2mol1

A
van der Waals constant a is a measure of attractive force
B
b is expressed in L mol1
C
van der Waals constant b is also called co-volume or excluded volume
D
a is expressed in atm L2mol1
Solution
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Van der Waals constant a is a indirect measure of attractive force. Gases with higher values of a can be easily liquified.
Van der Waals constant b is also called co-volume or excluded volume. It is the effective volume of a gas. When gas molecules have constant value of b over wider range of temperature and pressure, the gas molecules are incompressible.
b has units L mol1 or ml3 mol1.
The units of a are atm L2 mol1.

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