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Isomerism in Coordination Compounds

Question

Which of the following compounds will show metamerism?
$C H_{3} - C O - C_{2} H_{5}$
$C H_{3} - O - C H_{3}$
$C H_{3} - O - C_{2} H_{5}$
$C_{2} H_{5} - S - C_{2} H_{5}$

A

C H_{3} - O - C H_{3}

B

C H_{3} - C O - C_{2} H_{5}

C

C_{2} H_{5} - S - C_{2} H_{5}

D

C H_{3} - O - C_{2} H_{5}

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Solution

Verified by Toppr

Metamerism occurs when the compound has different number of carbon atoms on either side of the functional group.
Only option B can show metamerism.
$C_{2} H_{5} - S - C_{2} H_{5}$ is a metamer of $C H_{3} - S - C_{3} H_{7}$ .

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Which of the following compound give racemic mixture on nucleophilic substitution?

(a)

C H_{3} - C H | C_{2} H_{5} - B r

(b)

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(c)

C_{2} H_{5} - C H | C_{2} H_{5} - C H_{2} B r

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Q2

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(iii)

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Q3

Write IUPAC names of the following :

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Q5

IUPAC name of the $C H_{3} - O - C_{2} H_{5}$ is:

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