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Question

Which of the following halides undergoes hydrolysis?
  1. NF3
  2. PF3
  3. PF5
  4. NCl3

A
NCl3
B
PF3
C
PF5
D
NF3
Solution
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In NCl3, nitrogen and chlorine have almost same electronegativities resulting in non-polar bonds. Nitrogen does not have empty d-orbitals so the hydrolysis takes place with a donation of a lone pair of electrons by the nitrogen to the hydrogen atom of water.
NCl3 +H2O HOCl + NH3

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