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Question

Which of the following is a Sandmeyer reaction?
  1. 2C6H5ClCu2Cl2/HCl−−−−−−−C6H6+Cl2
  2. C6H5N2ClCu2Cl2/HCl−−−−−−−C6H5Cl+N2
  3. C6H5OHZndust−−−−C6H6+ZnO
  4. C6H5NO2+6[H]Sn/HCl−−−−C6H5NH2+2H2O

A
2C6H5ClCu2Cl2/HCl−−−−−−−C6H6+Cl2
B
C6H5N2ClCu2Cl2/HCl−−−−−−−C6H5Cl+N2
C
C6H5NO2+6[H]Sn/HCl−−−−C6H5NH2+2H2O
D
C6H5OHZndust−−−−C6H6+ZnO
Solution
Verified by Toppr

In Sandmeyer's reaction, an arenediazonium salt reacts with cuprous chloride in hydrochloric acid to form chlorobenzene.
So, option B is the correct answer.

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