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Question

Which of the following oxoacid of sulphur has $$- O - O -$$ linkage?

A
$$H_2SO_4$$, sulphuric acid
B
$$H_2S_2O_7$$, pyrosulphuric acid
C
$$H_2S_2O_8$$, peroxodisulphuric acid
D
$$H_2SO_3$$, sulphurous acid
Solution
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Correct option is B. $$H_2S_2O_8$$, peroxodisulphuric acid
$$OH-\overset{O}{\overset{||}{\underset{O}{\underset{||}{S}}}}-OH$$
$$H_2SO_4$$

$$OH-\overset{O}{\overset{||}{\underset{O}{\underset{||}{S}}}}-O-$$$$O-\overset{O}{\overset{||}{\underset{O}{\underset{||}{S}}}}-OH$$
$$H_2S_2O_8$$

$$HO-\overset{O}{\overset{||}{\underset{O}{\underset{||}{S}}}}$$$$-O-\overset{O}{\overset{||}{\underset{O}{\underset{||}{S}}}}-OH$$
$$H_2S_2O_7$$

$$OH-\overset{O}{\overset{||}{S}}-OH$$
$$H_2SO_3$$

As the structure shown $$H_2S_2O_8$$ contains $$-O-O-$$ linkage.

Option B is correct.

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