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Question

Which of the following oxo-acids of sulphur has maximum number of pπ- dπ bonds in it?
  1. H2S2O2
  2. H2S2O5
  3. H2S2O3
  4. H2S2O8

A
H2S2O3
B
H2S2O5
C
H2S2O8
D
H2S2O2
Solution
Verified by Toppr

Peroxydisulphuric acid (or Marshall's acid) H2S2O8 has maximum number (four) of pπ- dπ bonds in it.

H2S2O2 has one pπ- dπ bond. H2S2O3 and H2S2O5 has two and three pπ- dπ bonds respectively.

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