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Question

Which of the following represents the correct order of increasing pKa values of the given acids?
  1. HClO4<HNO3<H2CO3<B(OH)3
  2. HNO3<HClO4<B(OH)3<H2CO3
  3. B(OH)3<H2CO3<HClO4<HNO3
  4. HClO4<HNO3<B(OH)3<H2CO3

A
HClO4<HNO3<H2CO3<B(OH)3
B
HClO4<HNO3<B(OH)3<H2CO3
C
HNO3<HClO4<B(OH)3<H2CO3
D
B(OH)3<H2CO3<HClO4<HNO3
Solution
Verified by Toppr

As we know,
acidic strength of acids as
HClO4>HNO3>H2CO3>B(OH)3
+7 +5 +4
and as we know,
more stronger acid have lower value of pKa so
pKa order
HClO4<HNO3<H2CO3<B(OH)3

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