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Question

Which of the following solvents should be added to the organic solvent containing the pentane in order to remove the impurities in a separate layer that will not mix with the organic solvent?
  1. C6H6
  2. CCl4
  3. HF
  4. SH2

A
CCl4
B
C6H6
C
HF
D
SH2
Solution
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Due to its symmetrical structure, carbon tetrachloride (CCl4) is non-polar. Its non-polar nature makes it a suitable solvent for dissolving non-polar compounds. Carbon tetrachloride is convenient as a solvent for NMR because it contains no protons, however, its poor dissolving power limits its usefulness. As a solvent, it is well suited for dissolving other non-polar compounds, iodine, fats, and oils.

CCl4 can undergo various reactions like dimerization to Hexachloroethane, reduction to chloroform.

Hence, the correct option is A

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