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Question

Which of the following statement is correct?
  1. In peroxosulphuric acid (H2SO5) sulphur is in +8 oxidation state
  2. SS bond is present in H2S2O6
  3. Copper powder along with Al2O3 and K2O is used as a catalyst in the preparation of NH3 by Haber's process
  4. Change in enthalpy is positive for the preparation of SO3 by catalytic oxidation of SO2

A
SS bond is present in H2S2O6
B
Change in enthalpy is positive for the preparation of SO3 by catalytic oxidation of SO2
C
In peroxosulphuric acid (H2SO5) sulphur is in +8 oxidation state
D
Copper powder along with Al2O3 and K2O is used as a catalyst in the preparation of NH3 by Haber's process
Solution
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SS bond is present in H2S2O6. In H2SO5, the oxidation number of O is +6 as two O are having peroxide bond.
Preparation of SO3 by catalytic oxidation of SO2 is exothermic.

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