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Question

Which of these statements is not true?
  1. NO+ is isoelectronic with O2.
  2. B is always covalent in its compounds.
  3. In aqueous solution, the Tl+ ion is much more stable than TI(III).
  4. LiAlH4 is a versatile reducing agent in organic synthesis.

A
B is always covalent in its compounds.
B
NO+ is isoelectronic with O2.
C
LiAlH4 is a versatile reducing agent in organic synthesis.
D
In aqueous solution, the Tl+ ion is much more stable than TI(III).
Solution
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NO+ has 14 electrons and O2 has 16 electrons.Therefore, they are not isoelectronic species.

Boron is covalent in its compound.

Tl+ is much more stable than Tl3+ as going down the group the stability of lower oxidation number increases due to inert pair effect.

LiAlH4 is a selective reducing agent in organic synthesis.

Hence, option A is not true.

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