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Question

Which one of the following tests can be used to identify primary amino group in a given organic compound?
  1. Iodoform test
  2. Victor Meyer's test
  3. Carbylamine reaction
  4. Libermann's reaction

A
Libermann's reaction
B
Iodoform test
C
Victor Meyer's test
D
Carbylamine reaction
Solution
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Carbylamine reaction can be used to identify primary amino group in a given organic compound. When primary amines are treated with chloroform and alcoholic KOH, they give isocyanides (carbylamines) having very unpleasant smell which can be easily detected.
RNH2+CHCl3+3KOHRNC+3KCl+3H2O

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