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Question

Write an equation to show the reaction between Plaster of Paris and water?
  1. CaSO4.12H2OPlaster of Paris+32H2OWaterCaSO4.2H2OGypsum
  2. CaSO4.12H2OPlaster of Paris+12H2OWaterCaSO4.H2OGypsum
  3. CaSO4.H2OPlaster of Paris+H2OWaterCaSO4.2H2OGypsum
  4. CaSO4.H2OPlaster of Paris+32H2OWaterCaSO4.52H2OGypsum

A
CaSO4.H2OPlaster of Paris+32H2OWaterCaSO4.52H2OGypsum
B
CaSO4.12H2OPlaster of Paris+32H2OWaterCaSO4.2H2OGypsum
C
CaSO4.H2OPlaster of Paris+H2OWaterCaSO4.2H2OGypsum
D
CaSO4.12H2OPlaster of Paris+12H2OWaterCaSO4.H2OGypsum
Solution
Verified by Toppr

Plaster of Paris when reacts with water liberating heat through crystallization. Gypsum is produced by heating plaster of paris to about 150-degree Celsius. When the dry plaster of paris powder is mixed with water it reforms into gypsum. Depending upon the temperature gypsum converts to hemihydrate or anhydrous form.
CaSO4.12H2OPlaster of Paris+32H2OWaterCaSO4.2H2OGypsum

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Similar Questions
Q1
Match List - I with List - II for the compositions of substances and select the correct answer using the code given below the list:
List - I List - II
Substances Composition
(A) Plaster of paris (i) CaSO42H2O
(B) Epsomite (ii) CasO412H2O
(C) Kieserite (iii) MaSO47H2O
(D) Gypsum (iv) MgSO4H2O
(v) CaSO4
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Q2

List IList II1. Plaster of Parisa. CaSO4.2H2O2. Epsomiteb. CaSO4.1/2H2O3. Kieseritec. MgSO4.7H2O4. Gypsumd. MgSO4.H2Oe.CaSO4


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Q3

List IList II1. Plaster of Parisa. CaSO4.2H2O2. Epsomiteb. CaSO4.1/2H2O3. Kieseritec. MgSO4.7H2O4. Gypsumd. MgSO4.H2Oe.CaSO4


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Q4
Concrete is produced from a mixture of cement, water and small stones. A small amount of gypsum, CaSO42H2O is added in cement production to improve the subsequent hardening of concrete.
The elevated temperature during the production of cement may lead to the formation of unwanted hemihydrate CaSO412H2O according to reaction.
CaSO42H2O(s)CaSO412H2O(s)+32H2O(g)
The ΔfH of CaSO42H2O(s), CaSO412H2O(s), H2O(g) are 2021.0kJmol1, 1575.0kJmol1 and 241.8kJmol1 respectively. The respective values of their standard entropies are 194.0, 130.0 and 188.0JK1mol1.
R=8.314JK1mol1=0.0831Lbarmol1K1
Answer the follwoing questions on the basis of above information.
Heat change occuring during conversion of 1Kg of CaSO42H2O(s) (molar mass 172 g mol1) of CaSO412H2O(s) is equal to:
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Q5
Question 32
Match the important chemicals given in Column I with the chemical formulae given in Column II.
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