Electrochemistry

Cathode and Anode

An electrode is a substance that is in use for the conduction of electricity. The electric current comes or leaves the non-metallic medium like an electrolytic cell. In simple language, an electrode is a conductor that helps in establishing electrical contact with a non-metallic part of the circuit. Electrodes consist of two main things that are cathode and anode which basically describe the direction of flow of current. The terms anode and cathode are not given by the voltage polarity of electrodes but the direction of current through the electrode.

Cathode and Anode  

What is a Cathode?

It is an electrode from which a current leaves a polarized electrical device. This can be recalled by using the mnemonic Cathode Current Departs. A conventional current shows the direction in which positive charges move. Electrons have a negative electrical charge. Therefore, the movement of electrons is opposite to that of the current flow.

Example of cathode

The cathodic current is the flow of electrons from the cathode interface to a species in solution.

Electrolytic Cell

In an electrolytic cell, the cathode is where the negative polarity is applied. Some results of reduction at the cathode are pure metal or hydrogen gas from metal ions. While studying the relative reducing power of two redox agents, the couple for making the more reducing species is more cathodic with respect to the more easily reduced reagent.

Galvanic Cell

In a galvanic cell, the cathode is the positive pole. This positive pole is connected to allow the circuit to be completed. The anode of the galvanic cell gives off electrons and return from the circuit into the cell through the cathode.

Electroplating Metal Cathode (Electrolysis)

When metal ions are reduced, they form a pure metal surface on the cathode. Items to be plated with pure metal are attached and become part of the cathode in the solution.

Anode

An anode is an electrode by which the conventional current enters into a polarized electrical device. In contrasts with a cathode, an electrode by which conventional current leaves an electrical device. A common mnemonic is anode current into the device. The direction of current in a circuit is opposite to the direction of electron flow. Therefore, the negatively charged electrons flow out the anode of a galvanic cell, into an external circuit connected to the cell. In both a galvanic cell and an electrolytic cell, the anode is the electrode where oxidation reaction occurs.

In an electrolytic cell, the anode is the wire with a positive charge. Anions tend to move towards the anode where they can undergo oxidation. Historically, the anode was known as the zincode.

Examples of anode

  • In a discharging battery or galvanic cell, the anode is the negative terminal because it is where current flows into the cell. This inward current is carried by electrons moving outwards. The negative charge flowing in one direction is equivalent to the positive charge flowing in the opposite direction.
  • In a recharging battery, the anode is the positive terminal that receives current from an external generator. The current through a battery is opposite to the direction of current during discharge in the recharging battery. In simple words, the electrode that was the cathode while battery discharge becomes the anode during the battery is recharging.
  • In a diode, the anode is the positive terminal where the current flows into the device. The electrode naming for diodes is based on the direction of the forward current.
  • In vacuum tubes or gas-filled tubes, the anode is the terminal while the current enters the tube.

FAQs on Cathode and Anode

Question 1: What is the charge on anode and cathode?

Answer: Oxidation response at the anode. The oxidized species lose electrons by leaving electrode with an accumulation of electrons. Therefore, the anode has a negative charge. In contrast, a cathode is a reduction response where the decreased species obtain electrons. Therefore, the electrode, i.e., the cathode, lacks electrons and has a positive charge.

Question 2: What is the charge of an anode and cathode?

Answer: The anode is negative in a galvanic cell and the cathode is positive. It is because of the fact that anode is the origin of electrons and where the electrons flow is the cathode.

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Eileen

nice information. Can you please write the updated date and the author’s name for citation?

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